Title

Visualization of electrochemical reactions in battery materials with X-ray microscopy and mapping

Document Type

Article

Publication Date

2017

Abstract

Unlocking the full performance capabilities of battery materials will require a thorough understanding of the underlying electrochemical mechanisms at a variety of length scales. A broad arsenal of X-ray microscopy and mapping techniques is now available to probe these processes down to the nanoscale. The tunable nature of X-ray sources allows for the extraction of chemical states through spectromicroscopy. The addition of phase contrast imaging can retrieve the complex-valued refraction of the material, giving an even more nuanced chemical picture. Tomography and coherent Bragg diffraction imaging provide a reconstructed three-dimensional volume of the specimen, as well as internal strain information from the latter. Many recent insights into battery materials have been achieved through the creative use of these, and similar, methods. Experiments performed while the battery is being actively cycled reveal behavior that differs significantly from what is observed at equilibrium and metastable conditions. Planned improvements to X-ray source brightness and coherence will extend these techniques by alleviating the current trade-off in time, chemical, and spatial resolution

Comments

ACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes

Publisher Attribution

Final version of article available from ACS Publications via doi: 10.1021/acs.chemmater.6b05114